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Most Important Reactions in Organic Chemistry

Here’s a compact list of the most important basic organic chemistry reactions (just the reactions, no explanations):

  1. Combustion:
    CxHy+O2CO2+H2O\text{C}_x\text{H}_y + O_2 \rightarrow CO_2 + H_2O

  2. Halogenation of Alkanes (Free Radical Substitution):
    CH4+Cl2hvCH3Cl+HCl\text{CH}_4 + Cl_2 \xrightarrow{hv} \text{CH}_3Cl + HCl

  3. Hydrogenation of Alkenes:
    CH2=CH2+H2 →Ni/Pt    CH3CH3\text{CH}_2=CH_2 + H_2 \xrightarrow{Ni/Pt} CH_3CH_3

  4. Halogenation of Alkenes (Electrophilic Addition):
    CH2=CH2+Br2BrCH2CH2Br\text{CH}_2=CH_2 + Br_2 \rightarrow BrCH_2CH_2Br

  5. Hydration of Alkenes:
    CH2=CH2+H2OH+CH3CH2OH\text{CH}_2=CH_2 + H_2O \xrightarrow{H^+} CH_3CH_2OH

  6. Ozonolysis of Alkenes:
    RCH=CHR’+O3RCHO+RCHO\text{RCH=CHR'} + O_3 \rightarrow RCHO + R'CHO

  7. Dehydration of Alcohols:
    CH3CH2OHH2SO4,Δ          CH2=CH2+H2O\text{CH}_3CH_2OH \xrightarrow{H_2SO_4, \Delta} CH_2=CH_2 + H_2O

  8. Oxidation of Alcohols:
    CH3CH2OH[O] CH3CHO[O] CH3COOH\text{CH}_3CH_2OH \xrightarrow{[O]} CH_3CHO \xrightarrow{[O]} CH_3COOH

  9. Haloform Reaction:
    CH3COCH3+3I2+4NaOHCHI3+CH3COONa+3NaI+3H2O\text{CH}_3COCH_3 + 3I_2 + 4NaOH \rightarrow CHI_3 + CH_3COONa + 3NaI + 3H_2O

  10. Cannizzaro Reaction:
    2HCHONaOH      CH3OH+HCOONa\text{2HCHO} \xrightarrow{NaOH} CH_3OH + HCOONa

  11. Aldol Condensation:
    2CH3CHONaOH      CH3CH(OH)CH2CHOΔCH3CH=CHCHO\text{2CH}_3CHO \xrightarrow{NaOH} CH_3CH(OH)CH_2CHO \xrightarrow{\Delta} CH_3CH=CHCHO

  12. Kolbe’s Reaction:
    C6H5ONa+CO2Δo-HO–C6H4–COONa\text{C}_6\text{H}_5ONa + CO_2 \xrightarrow{\Delta} \text{o-HO–C}_6\text{H}_4\text{–COONa}

  13. Reimer–Tiemann Reaction:
    C6H5OH+CHCl3+NaOHoHOC6H4CHO\text{C}_6\text{H}_5OH + CHCl_3 + NaOH \rightarrow o-HO–C_6H_4–CHO

  14. Friedel–Crafts Alkylation:
    C6H6+RClAlCl3     C6H5R+HCl\text{C}_6\text{H}_6 + RCl \xrightarrow{AlCl_3} C_6H_5R + HCl

  15. Friedel–Crafts Acylation:
    C6H6+RCOClAlCl3      C6H5COR+HCl\text{C}_6\text{H}_6 + RCOCl \xrightarrow{AlCl_3} C_6H_5COR + HCl

  16. Sandmeyer Reaction:
    ArN2+ClCuCl/HCl           ArCl\text{ArN}_2^+Cl^- \xrightarrow{CuCl/HCl} ArCl

  17. Wurtz Reaction:
    2RCl + 2NaRR+2NaCl\text{2RCl + 2Na} \rightarrow R–R + 2NaCl

  18. Kolbe Electrolysis:
    2CH3COONaelectrolysis           C2H6+2CO2+H2\text{2CH}_3COONa \xrightarrow{electrolysis} C_2H_6 + 2CO_2 + H_2



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